Jolie is expected to arrive in Istanbul and head to Hatay on Friday, according to the ministry, which accepted an application for her visit on Wednesday.
More than 8,000 Syrians have fled their country for Turkey to escape violence, including a military offensive in the Jisr al-Shugur area.
Jolie was named a goodwill ambassador for the Office of the U.N. High Commissioner for Refugees in early 2001 and has visited more than 20 countries "to highlight the plight of millions of uprooted people and to advocate for their protection."
The U.N. office said her interest in "humanitarian affairs was piqued in 2000 when she went to Cambodia to film the adventure film 'Tomb Raider.' "
Jolie has won numerous acting awards, including a best supporting actress Academy Award for her performance in 1999's "Girl, Interrupted."
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